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- W2073266481 abstract "2-Phenylbenzophenone is proposed to have two nearby triplets, a low lying π,π* state similar to that of biphenyl and a benzophenone-like triplet lying ~4 kcal/mol higher. The triplet lifetimes of this photostable ketone are extremely short, e.g. 0.56 and 2.5 ns at 300 K in toluene and isooctane, respectively, and are believed to be controlled by population of the benzophenone-like triplet and decay from this state via interaction of the carbonyl chromophore with the phenyl ring in the ortho position. The two triplets interconvert via ring rotation. The Arrhenius parameters for triplet decay in five solvents show some dependency with the temperature dependence of the solvent viscosity." @default.
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- W2073266481 date "1984-11-01" @default.
- W2073266481 modified "2023-10-14" @default.
- W2073266481 title "Photochemistry of 2-phenylbenzophenone. An unusual bichromophoric molecule" @default.
- W2073266481 doi "https://doi.org/10.1139/v84-401" @default.
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