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- W2073285644 abstract "The hydrolytic behavior of titanium and zirconium monocarbonitrides at high temperatures has been studied and compared with that of monocarbides and mononitrides of titanium and zirconium.In the hydrolysis of carbonitride, the gaseous products are found to consist of H2, N2, CO, CO2 and a small amount of CH4, while liquid fraction involves NH3 and a very small amount of CH3NH2. A remarkable feature for zirconium carbonitride is the formation of NH3, N2 and CO in the earlier period of the reaction with the succeeding evolution of CO2. From measurements of weight changes and by X-ray diffraction it is concluded that a large fraction of carbon precipitates as elementary carbon in the early stage of the hydrolysis and reacts with water vapor in the succeeding stage.A general relation between the compound under hydrolysis and the chemical species of main primary products is presented; more covalent carbonitrides (such as TiC) have stronger inclination to form N2 and carbon oxides under hydrolysis and more ionic materials are apt to produce more NH3 and hydrocarbons." @default.
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- W2073285644 date "1977-01-01" @default.
- W2073285644 modified "2023-09-27" @default.
- W2073285644 title "Hydrolysis of Titanium and Zirconium Carbonitrides" @default.
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- W2073285644 doi "https://doi.org/10.2320/matertrans1960.18.727" @default.
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