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• W2073740552 abstract "Alkylidene complexes (Me3SiCH2)3Ta(PMe3)CHSiMe3 (1) and Me3SiCH2Ta(PMe3)2(CHSiMe3)2 (3a) were found to react with phenylsilanes H2SiR′Ph (R′=Me, Ph) and (PhSiH2)2CH2 to give disilyl-substituted alkylidenes (Me3SiCH2)3TaC(SiMe3)(SiHR′Ph) (2) and novel metallasilacyclobutadiene and metalladisilacyclohexadiene complexes. Silyl-substituted alkylidene complex (ButCH2)2W(O)[C(But)(SiPh2But)] (5a) was prepared from the reaction of O2 with an equilibrium mixture (ButCH2)W(CHBut)2(SiPh2But) (4b) ⇔ (ButCH2)2W(CBut)(SiPh2But) (4a). Our recent studies of the preparation of these complexes and mechanistic pathways in the formation of these silyl-substituted alkylidene complexes are summarized." @default.
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• W2073740552 date "2002-12-01" @default.
• W2073740552 modified "2023-10-14" @default.
• W2073740552 title "Silyl-substituted alkylidenes: preparation of the novel complexes and mechanistic studies of their formation from reactions of alkylidenes with silanes and silyl-to-alkylidyne migration" @default.
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• W2073740552 doi "https://doi.org/10.1016/s1381-1169(02)00221-2" @default.
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