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• W2074844039 abstract "The reaction between the titananorbornadiene complex [(DMSC)Ti(η6-1,2,4-(Me3Si)3C6H3)] (2) and ketones or aldehydes proceeds by insertion of a ketone or aldehyde molecule into a Ti−C bond of 2, yielding 2,5-dioxatitanacyclopentane or 2-oxatitanacycloheptene compounds. The intermediacy of a 2-oxatitanacycloheptene species en route to arene loss from 2 and the formation of 2,5-dioxatitanacyclopentane compounds are indicated." @default.
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• W2074844039 date "2000-09-13" @default.
• W2074844039 modified "2023-10-11" @default.
• W2074844039 title "Reactivity of a Well-Characterized Titananorbornadiene (η⁶-Arene) Complex with Ketones and Aldehydes" @default.
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• W2074844039 doi "https://doi.org/10.1021/om000410w" @default.
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