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- W2074994052 abstract "Energies of combustion at 298.15 K were measured for 1-dodecene and 1-hexadecene and the following enthalpies of formation were derived for the compounds in the liquid and gaseous states (uncertainties given represent twice the overall standard deviation of the mean): ΔHfo(l)/kJ mol−1ΔHfo(g)/kJ mol−11-dodecene−226.2±2.1−165.4±2.11-hexadecene−330.5±3.0−250.2±3.0 A least-squares analysis of available enthalpy-of-formation values for 1-butene and higher members,(1 – 6, 9) on the assumption of a constant CH2-increment, gives: δH°f{C2H3(CH2)mH,g}/kJ mol−=(941.18±0.700)−(20.669±0.147)m, (m⩾) where the uncertainties represent twice the calculated standard deviations. The increment found was in good agreement with the “accepted” value, −20.610 kJ mol−1.(11)" @default.
- W2074994052 created "2016-06-24" @default.
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- W2074994052 date "1976-09-01" @default.
- W2074994052 modified "2023-09-26" @default.
- W2074994052 title "Enthalpies of formation of 1-dodecene and 1-hexadecene and the CH2-increment in the 1-alkene series" @default.
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- W2074994052 doi "https://doi.org/10.1016/0021-9614(76)90167-1" @default.
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