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- W2076585293 abstract "Abstract Semibatch starved‐feed solution copolymerization is used to produce acrylic resins for coatings formulations. Mechanisms and rate coefficients for polymerization of methacrylates, acrylates, and styrene (ST) under these high‐temperature conditions are reviewed. An extended set of experimental results at 138 °C is used to refine a model describing the solution copolymerization of ST and methacrylates. The data suggest that both changing initiator efficiency and transfer reactions of oxygen‐centered radicals to polymer affect the development of polymer molecular weight. A penultimate model is used to describe the variation in termination rate coefficient with copolymer composition. Significant progress has been made to develop an extended model capable of representing multicomponent high‐temperature acrylic polymerizations. magnified image" @default.
- W2076585293 created "2016-06-24" @default.
- W2076585293 creator A5046597133 @default.
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- W2076585293 date "2008-06-16" @default.
- W2076585293 modified "2023-10-14" @default.
- W2076585293 title "Recent Advances in the Study of High-Temperature Free Radical Acrylic Solution Copolymerization" @default.
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- W2076585293 doi "https://doi.org/10.1002/mren.200700051" @default.
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