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- W2077125785 abstract "Abstract Reactions of head‐to‐head (HH) α‐pyridonato‐ and pivalamidato‐bridged platinum(III) binuclear complexes withacetone were investigated kinetically. The reactions with acetone proceeded slowly to form acetonyl Pt III binuclear complexes in two steps. A mechanism, which involves π‐coordination of the enol form of acetone in the first step, followed by the π–σ bond conversion in the second step, is proposed. π‐Coordination of the enol was strongly supported by kinetic analyses of a ligand substitution reaction involving the pivalamidato‐bridged Pt III binuclear complex with (4‐hydroxyphenyl)pyruvic acid. Only the enol form was reactive towards the Pt III dimer complex." @default.
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- W2077125785 date "2011-03-14" @default.
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- W2077125785 title "Formation Mechanism of Head‐to‐Head Amidato‐Bridged Acetonylplatinum(III) Binuclear Complexes – Kinetic Evidence for π‐Coordination of the Enol Form of a Ketone in a Ligand Substitution Reaction" @default.
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- W2077125785 doi "https://doi.org/10.1002/ejic.201001089" @default.
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