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- W2077474474 abstract "Abstract The first nucleophilic addition of an inorganic nucleophile (cyanide) to the activated, rigid, α ‐diazomethine groups of a 1,2,5‐thiadiazole 1,1‐dioxide is reported here. An α ‐amino nitrile and a bis α ‐amino nitrile derivatives were obtained in good yields (62 and 98%, respectively) and characterized by spectroscopic, analytical, and single crystal X‐ray diffraction techniques. The course of the reaction, followed by cyclic voltammetry (CV), showed that cyanide adds to only one of the two CN double bonds of the thiadiazole, forming an anion from which an N ‐methyl derivative was obtained. Adequate concentrations of cyanide and methyl iodide (MeI) produced directly the bis α ‐amino nitrile derivative. Copyright © 2007 John Wiley & Sons, Ltd." @default.
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- W2077474474 date "2007-09-25" @default.
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- W2077474474 title "Synthesis of anα-amino nitrile and a bisα-amino nitrile derivative of thiadiazole: reaction mechanism" @default.
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- W2077474474 doi "https://doi.org/10.1002/poc.1257" @default.
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