FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078209717> ?p ?o ?g. }

• W2078209717 endingPage "102" @default.
• W2078209717 startingPage "94" @default.
• W2078209717 abstract "Photolysis of dibenzothiophene sulfoxide results in the formation of dibenzothiophene and oxidized solvent. Though quantum yields are low, chemical yields of the sulfide are quite high. Yields of the oxidized solvents can also be high. Typical products are phenol from benzene, cyclohexanol, and cyclohexene from cyclohexane and 2-cyclohexenol and epoxycyclohexane from cyclohexene. A number of experiments designed to elucidate the mechanism of the hydroxylation were carried out, including measurements of quantum yields as a function of concentration, solvent, quenchers, and excitation wavelength. These data are inconsistent with a mechanism involving a sulfoxide dimer, which also does not properly account for the solvent oxidations. It is suggested that the active oxidizing agent may be atomic oxygen O(3P) or a closely related noncovalent complex, based on the nature of the oxidation chemistry, comparison to known rate constants for O(3P) reactivity, and the quantum yield data." @default.
• W2078209717 created "2016-06-24" @default.
• W2078209717 creator A5027847955 @default.
• W2078209717 creator A5030274345 @default.
• W2078209717 creator A5037990226 @default.
• W2078209717 date "1997-01-01" @default.
• W2078209717 modified "2023-10-18" @default.
• W2078209717 title "Photodeoxygenation of Dibenzothiophene Sulfoxide: Evidence for a Unimolecular S−O Cleavage Mechanism¹" @default.
• W2078209717 cites W1643981441 @default.
• W2078209717 cites W1987758438 @default.
• W2078209717 cites W1998575940 @default.
• W2078209717 cites W2001870437 @default.
• W2078209717 cites W2026132326 @default.
• W2078209717 cites W2026675311 @default.
• W2078209717 cites W2048414598 @default.
• W2078209717 cites W2053545615 @default.
• W2078209717 cites W2057682338 @default.
• W2078209717 cites W2061427955 @default.
• W2078209717 cites W2069940149 @default.
• W2078209717 cites W2073356400 @default.
• W2078209717 cites W2085079874 @default.
• W2078209717 cites W2109392153 @default.
• W2078209717 cites W2322405971 @default.
• W2078209717 cites W2330432636 @default.
• W2078209717 cites W2331000569 @default.
• W2078209717 cites W2334807634 @default.
• W2078209717 cites W3004473382 @default.
• W2078209717 cites W4251038045 @default.
• W2078209717 doi "https://doi.org/10.1021/ja962975i" @default.
• W2078209717 hasPublicationYear "1997" @default.
• W2078209717 type Work @default.
• W2078209717 sameAs 2078209717 @default.
• W2078209717 citedByCount "81" @default.
• W2078209717 countsByYear W20782097172012 @default.
• W2078209717 countsByYear W20782097172013 @default.
• W2078209717 countsByYear W20782097172014 @default.
• W2078209717 countsByYear W20782097172015 @default.
• W2078209717 countsByYear W20782097172016 @default.
• W2078209717 countsByYear W20782097172017 @default.
• W2078209717 countsByYear W20782097172018 @default.
• W2078209717 countsByYear W20782097172019 @default.
• W2078209717 countsByYear W20782097172020 @default.
• W2078209717 countsByYear W20782097172021 @default.
• W2078209717 countsByYear W20782097172022 @default.
• W2078209717 countsByYear W20782097172023 @default.
• W2078209717 crossrefType "journal-article" @default.
• W2078209717 hasAuthorship W2078209717A5027847955 @default.
• W2078209717 hasAuthorship W2078209717A5030274345 @default.
• W2078209717 hasAuthorship W2078209717A5037990226 @default.
• W2078209717 hasConcept C121332964 @default.
• W2078209717 hasConcept C161790260 @default.
• W2078209717 hasConcept C171001562 @default.
• W2078209717 hasConcept C178790620 @default.
• W2078209717 hasConcept C185592680 @default.
• W2078209717 hasConcept C2776606100 @default.
• W2078209717 hasConcept C2778237882 @default.
• W2078209717 hasConcept C2778448320 @default.
• W2078209717 hasConcept C2778452553 @default.
• W2078209717 hasConcept C2778949310 @default.
• W2078209717 hasConcept C2779484182 @default.
• W2078209717 hasConcept C2780471494 @default.
• W2078209717 hasConcept C518881349 @default.
• W2078209717 hasConcept C62520636 @default.
• W2078209717 hasConcept C65024703 @default.
• W2078209717 hasConcept C75473681 @default.
• W2078209717 hasConcept C77176794 @default.
• W2078209717 hasConcept C91881484 @default.
• W2078209717 hasConceptScore W2078209717C121332964 @default.
• W2078209717 hasConceptScore W2078209717C161790260 @default.
• W2078209717 hasConceptScore W2078209717C171001562 @default.
• W2078209717 hasConceptScore W2078209717C178790620 @default.
• W2078209717 hasConceptScore W2078209717C185592680 @default.
• W2078209717 hasConceptScore W2078209717C2776606100 @default.
• W2078209717 hasConceptScore W2078209717C2778237882 @default.
• W2078209717 hasConceptScore W2078209717C2778448320 @default.
• W2078209717 hasConceptScore W2078209717C2778452553 @default.
• W2078209717 hasConceptScore W2078209717C2778949310 @default.
• W2078209717 hasConceptScore W2078209717C2779484182 @default.
• W2078209717 hasConceptScore W2078209717C2780471494 @default.
• W2078209717 hasConceptScore W2078209717C518881349 @default.
• W2078209717 hasConceptScore W2078209717C62520636 @default.
• W2078209717 hasConceptScore W2078209717C65024703 @default.
• W2078209717 hasConceptScore W2078209717C75473681 @default.
• W2078209717 hasConceptScore W2078209717C77176794 @default.
• W2078209717 hasConceptScore W2078209717C91881484 @default.
• W2078209717 hasIssue "1" @default.
• W2078209717 hasLocation W20782097171 @default.
• W2078209717 hasOpenAccess W2078209717 @default.
• W2078209717 hasPrimaryLocation W20782097171 @default.
• W2078209717 hasRelatedWork W1987758438 @default.
• W2078209717 hasRelatedWork W2004599238 @default.
• W2078209717 hasRelatedWork W2007439908 @default.
• W2078209717 hasRelatedWork W2037752776 @default.
• W2078209717 hasRelatedWork W2055540236 @default.
• W2078209717 hasRelatedWork W2063342960 @default.
• W2078209717 hasRelatedWork W2078209717 @default.
• W2078209717 hasRelatedWork W2083245313 @default.
• W2078209717 hasRelatedWork W2091815229 @default.

• next