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• W2081389611 abstract "Effects of cation-site vacancies on the characteristics of the cubic–tetragonal displacive transitions in La-modified PbTiO3 (PLT) were studied using in situ XRD measurements and Raman scattering. For this purpose, two distinct types of PLT series having cation-site vacancies either at the A site (PLT-A) or at the B site (PLT-B) were separately prepared. The PLT-A series exhibited normal ferroelectricity and underwent the cubic-to-tetragonal structural transition for La substitution up to 30 at. %. Contrary to this, the PLT-B became a typical relaxor with the absence of the macroscopic cubic–tetragonal transition. However, for both types of PLTs, Raman-forbidden bands appeared in the high-temperature cubic-phase field at 30 at. % La modification. These observations were attributed to the formation of short-ranged clusters with tetragonal symmetry in a globally cubic matrix and to the reduced dipolar interaction between the clusters in the PLT-B, as compared with the PLT-A." @default.
• W2081389611 created "2016-06-24" @default.
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• W2081389611 date "2002-01-01" @default.
• W2081389611 modified "2023-10-09" @default.
• W2081389611 title "Effects of La doping on the cubic–tetragonal phase transition and short-range ordering in PbTiO3" @default.
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• W2081389611 doi "https://doi.org/10.1063/1.1421206" @default.
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