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• W2083007053 abstract "Mixtures of di-(perdeuteropalmitoyl)-sn-glycero-3 choline ([2H62]Pam2GroPCho) with palmitoylcarnitine or palmitoyl-CoA in aqueous suspension have been examined by Fourier-transform infrared spectroscopy. The C-H (or C-D) region of the spectrum shows that an order-disorder transition exists in pure aqueous palmitoylcarnitine at 45 degrees C; palmitoylcarnitine mixes with [2H62]Pam2GroPCho without perturbing the gel-fluid transition of the phospholipid even at [2H62]Pam2GroPCho/palmitoylcarnitine 1:2 molar ratios; and palmitoyl-CoA, however, at similar proportions, smears out the [2H62]Pam2GroPCho transition as detected from C-D stretching vibrations. Relevant data from the carbonyl region include; the high-frequency (non-hydrogen bound) carbonyl subpopulation, but not the low frequency one, detects the gel-to-fluid transition of the phospholipid; the carbonyl region detects the thermotropic transition over a wider temperature range than the methylene stretching region, i.e. detects changes starting well below and ending several degrees above the methylene transition temperature, and a significant interaction may occur between some coenzyme A group and the carbonyl groups of the phospholipid. The latter interaction may contribute to explain the coenzyme A/carnitine exchange during mitochondrial fatty acid import." @default.
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• W2083007053 date "1995-07-01" @default.
• W2083007053 modified "2023-10-17" @default.
• W2083007053 title "An Infrared Investigation of Palmitoyl-Coenzyme A and Palmitoylcarnitine Interaction with Perdeuterated-Chain Phospholipid Bilayers" @default.
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• W2083007053 doi "https://doi.org/10.1111/j.1432-1033.1995.0199f.x" @default.
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