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• W2083646040 abstract "The solvation and ion pair nature of α-(phenylthio)benzyllithium (2d) in THF solution were investigated by NMR-spectroscopic methods. The effect of additives such as diethylene-glycol dimethyl ether or of 12-crown-4 was studied. The results were compared to those of benzyllithium compounds 4 and 6, containing a pentaoxapentadecane ansa chain. These compounds exist as contact ion pairs in which lithium is held at the anionic carbon. This is reflected in the 6Li,13C coupling and 1H,6Li-HOESY contacts in the NMR spectra." @default.
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• W2083646040 date "1995-06-01" @default.
• W2083646040 modified "2023-10-16" @default.
• W2083646040 title "Chiral Organometallic Reagents, XIII. Structural Aspects of Differentially Solvated Benzyllithium Contact Ion Pairs" @default.
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• W2083646040 doi "https://doi.org/10.1002/cber.19951280604" @default.
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