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- W2086560746 abstract "A homochiral microporous material is presented. The phase has 47% permanently porous void volume and is shown to have >1 nm diameter pores with three-dimensional channels using probe molecule sorption. Enantioselective guest sorption is strongly dependent on guest size. The homochiral microporous phase was identified by reactive selection from a first-generation chiral but nonporous framework. Chiral permanent porosity is established by directional noncovalent interactions between framework-forming and nonframework forming components of the stable second-generation material, which become stronger upon loss of the guests from the pore system." @default.
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- W2086560746 date "2004-04-27" @default.
- W2086560746 modified "2023-10-14" @default.
- W2086560746 title "Permanent Microporosity and Enantioselective Sorption in a Chiral Open Framework" @default.
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- W2086560746 doi "https://doi.org/10.1021/ja0316420" @default.
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