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- W2093473380 abstract "The title compounds 3-5 are accessible by treatment of P(C6H4CH2NMe2)3(1) with CuX (2a: X = Cl, 2b: X = Br, 2c: X = I) in the ratio of 1:1 or 1:2 in very good yields. Reaction of 1 with equimolar amounts of 2a affords the copper(I) chloride [P(C6H4CH2NMe2)3]CuCl (3). With a further equivalent of 2a homobimetallic [P(C6H4CH2NMe2)3]Cu2Cl2 (4) is formed, which also can be synthesized by the reaction of 1 with two equivalents of 2a. Complex 3 reacts with CuX (X = Br, I)to afford [P(C6H4CH2NMe2)3]Cu2ClX (5a: X = Br; 5b: X = I) in which mixed halides are present. The newly synthesized complexes 3-5 were characterized by elemental analyses, by their IR-, 1H-, 13C{1H}- and 31P{1H}-NMR spectra as well as by mass spectrometrical studies. The solid-state structures of complexes 3 and 4 are reported. Mononuclear 3 crystallizes in the monoclinic space group P21/c with the cell parameters a = 14.285(2), b = 10.853(2), c = 17.425(2) Å , β = 103.310(10)?, V = 2628.9(7) Å 3 and Z = 4 with 4053 observed unique reflections; R1 = 0.0314. The crystal structure of 3 consists of monomeric molecules with planar coordinated copper(I) centres (CuClNP). Homobimetallic 4 crystallizes in the monoclinic space group P21/n with a = 23.905(4), b = 10.874(3), c = 25.314(5), β = 99.130(10)?, V = 6497(2) /Aring; 3 and Z = 4 with 9021 observed unique reflections; R1 = 0.0480. In 4 one of two copper(I) centres possesses a distorted trigonal-pyramidal environment, while the other one is almost square-pyramidal coordinated. The Cu2Cl2 segment resembles to a building block which is set up by a contact ion pair consisting of Cu+ and [CuCl2]- , respectively." @default.
- W2093473380 created "2016-06-24" @default.
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- W2093473380 date "2002-02-01" @default.
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- W2093473380 title "Einkernige und zweikernige Kupfer(I)-Komplexe vom Typ LCuCl, LCu2Cl2 und LCu2ClX [L = P(C6H4CH2NMe2-2)3; X = Br, I]" @default.
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- W2093473380 doi "https://doi.org/10.1002/1521-3749(200202)628:2<349::aid-zaac349>3.0.co;2-r" @default.
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