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- W2094347913 abstract "A number of α,β-epoxy sulfoxides and epoxy sulfones have been prepared via cyclization of α-chloro-β-hydroxy sulfoxides or phase-transfer catalyzed reaction between α-chloroalkyl sulfones and carbonyl compounds. Thermal and acid-catalyzed rearrangement of these epoxides resulted in migration of sulfinyl or sulfonyl groups to form β-carbonyl sulfoxides or sulfones. Upon treatment of the epoxy sulfones with MgBr 2 in ether, α-bromocarbonyl compounds were obtained in excellent yield. The reaction of epoxy sulfones with nucleophiles was also briefly investigated." @default.
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- W2094347913 date "1979-02-01" @default.
- W2094347913 modified "2023-10-03" @default.
- W2094347913 title "α,β-Epoxy sulfoxides and sulfones. Synthesis and some reactions" @default.
- W2094347913 doi "https://doi.org/10.1139/v79-044" @default.
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