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- W2094448406 abstract "New proton and electron donors, M(II)(HL)(2) (M = Ni, Pd, Pt; L = 5,6-diethylpyradzinedithiolate), as well as a proton and electron acceptor, Pt(IV)(L)(2), were prepared and characterized. The pH-dependent cyclic voltammetry of the M(II)(HL)(2) complexes revealed a favorable Gibbs free energy (K(com) > 1) for the proton and electron transfer reactions from M(II)(HL)(2) to M(IV)(L)(2); i.e., the equilibrium for the following reaction lies to the right: M(II)(HL)(2) + M(IV)(L)(2) <==>2M(III)(HL)(L)." @default.
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- W2094448406 date "2004-10-16" @default.
- W2094448406 modified "2023-10-11" @default.
- W2094448406 title "Synthesis, Structure, and Cooperative Proton−Electron Transfer Reaction of Bis(5,6-diethylpyrazinedithiolato)metal Complexes (M = Ni, Pd, Pt)" @default.
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- W2094448406 doi "https://doi.org/10.1021/ic049621+" @default.
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