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- W2103740641 abstract "Reaction of the ligand (L) benzothiazole (bt) and 6-nitrobenzothiazole (nbt) with Ag[NO3] or Ag[ClO4] affords ionic complexes of formula [AgL][NO3] and [AgL2]X (X = NO3 or ClO4). The [Ag(nbt)][NO3] and [Ag(nbt)2]X complexes react with alcohols (MeOH, EtOH, or PhCH2OH) at room temperature to give ring-opening reactions and 2-amino-5-nitrobenzenethiolatosilver(I)via the corresponding 2-(methoxymethylene)amino-derivative. This is the first example of a thiazole ring-opening reaction in non-basic media." @default.
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- W2103740641 date "1976-01-01" @default.
- W2103740641 modified "2023-09-27" @default.
- W2103740641 title "Chemistry of the benzothiazole system: ring-opening reaction in a non-basic medium promoted by co-ordination to silver(I)" @default.
- W2103740641 doi "https://doi.org/10.1039/dt9760001203" @default.
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