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• W2109264885 abstract "Abstract Infrared quantum cutting involving Yb 3+ 950–1,000 nm ( 2 F 5/2 → 2 F 7/2 ) and Ho 3+ 1,007 nm ( 5 S 2 , 5 F 4 → 5 I 6 ) as well as 1,180 nm ( 5 I 6 → 5 I 8 ) emissions is achieved in BaGdF 5 : Ho 3+ , Yb 3+ nanoparticles which are synthesized by a facile hydrothermal route. The mechanisms through first- and second-order energy transfers were analyzed by the dependence of Yb 3+ doping concentration on the visible and infrared emissions, decay lifetime curves of the 5 F 5 → 5 I 8 , 5 S 2 / 5 F 4 → 5 I 8 , and 5 F 3 → 5 I 8 of Ho 3+ , in which a back energy transfer from Yb 3+ to Ho 3+ is first proposed to interpret the spectral characteristics. A modified calculation equation for quantum efficiency of Yb 3+ -Ho 3+ couple by exciting at 450 nm was presented according to the quantum cutting mechanism. Overall, the excellent luminescence properties of BaGdF 5 : Ho 3+ , Yb 3+ near-infrared quantum cutting nanoparticles could explore an interesting approach to maximize the performance of solar cells." @default.
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• W2109264885 date "2012-11-22" @default.
• W2109264885 modified "2023-10-17" @default.
• W2109264885 title "Near-infrared quantum cutting in Ho3+, Yb3+-codoped BaGdF5 nanoparticles via first-and second-order energy transfers" @default.
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• W2109264885 doi "https://doi.org/10.1186/1556-276x-7-636" @default.
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