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- W2119030710 abstract "Abstract Gamma ray induced polymerization of N,N'-methylenebisacrylamide (MBA) in aqueous solution has been studied. Rates of polymerization have been determined as a function of dose, dose rate, and monomer concentration. Polymerization mechanism was found to be free radical with chain propagation step involving ring formation. About 90% conversion was achieved in 25 minutes of irradiation (dose rate 1.54 × 1018 eV dm−3 s−1) of MBA solution (36 mmol). The polymerization rates were found to vary from 1.9 × 10 4 to 5.6 × 10−4 mol dm−3 s−1 when the monomer concentrations were varied between 80–164 mmols. The value of the constant kp/kt 1/2 was calculated to be 9.85 for the dose rate of 1.54 × 1018 eV dm−3 s−1. The precipitated polymer showed mono disperse particles of diameter of about 170 nm. The polymer was found to be highly crosslinked and insoluble in any solvent." @default.
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- W2119030710 date "1997-12-01" @default.
- W2119030710 modified "2023-09-24" @default.
- W2119030710 title "Radiation Induced Polymerization of N,N'-Methylenebisacrylamide in Aqueous Solution" @default.
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