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• W2138423184 endingPage "115501" @default.
• W2138423184 startingPage "115501" @default.
• W2138423184 abstract "We report very small (27)Al metallic shifts in a series of Cu-Zr-Al bulk metallic glasses. This observation and the Korringa type of spin-lattice relaxation behavior suggest that s-character wavefunctions weakly participate in bonding and opens the possibility of enhanced covalency (pd hybridization) with increasing Al concentration, in good agreement with elastic constants and hardness measurements. Moreover, ab initio calculations show that this bonding character originates from the strong Al 3p band and Zr 4d band hybridization since their atomic energy levels are closer to each other while the Al 3s band is localized far below the Fermi level. This study might provide a chemical view for understanding flow and fracture mechanisms of these bulk glass-forming alloys." @default.
• W2138423184 created "2016-06-24" @default.
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• W2138423184 date "2011-03-01" @default.
• W2138423184 modified "2023-09-23" @default.
• W2138423184 title "Bonding characters of Al-containing bulk metallic glasses studied by²⁷Al NMR" @default.
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• W2138423184 doi "https://doi.org/10.1088/0953-8984/23/11/115501" @default.
• W2138423184 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21358030" @default.
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