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- W2145356726 abstract "Abstract Neutral 4‐iodo‐ N ‐ethylimidazole 3 oxidatively adds to [Pt(PPh 3 ) 4 ] to give, in the presence of different tetraalkylammonium salts, complexes trans‐[ 4 ], trans‐[ 5 ], and trans‐[ 6 ] containing an anionic C4‐bound heterocycle with an unsubstituted ring‐nitrogen atom. Complex trans‐[ 4 ] reacts with the proton source NH 4 I under protonation of the ring‐nitrogen atom to produce complex trans‐[ 7 ]I which bears an NH,NR‐substituted aNHC ligand. The reaction of trans‐[ 4 ] with CH 3 I yields the complex trans‐[ 8 ]I which has a classical aNHC ligand with two alkylated ring‐nitrogen atoms." @default.
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- W2145356726 date "2015-09-25" @default.
- W2145356726 modified "2023-10-18" @default.
- W2145356726 title "Synthesis of Complexes with Abnormal “Protic” N-Heterocyclic Carbenes" @default.
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- W2145356726 doi "https://doi.org/10.1002/anie.201507206" @default.
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