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• W2146229087 abstract "Aryl-substituted epoxides undergo smooth rearrangement in the presence of 0.01–0.1 mol% Bi(OTf)3·xH2O. The rearrangement is regioselective with aryl-substituted epoxides, and products arise from cleavage of the benzylic CO bond. The highly catalytic nature of this method coupled with the fact that the reagent is relatively non-toxic, easy to handle and inexpensive make it an attractive alternative to more corrosive and toxic Lewis acids, such as BF3·Et2O, currently used to effect epoxide rearrangements." @default.
• W2146229087 created "2016-06-24" @default.
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• W2146229087 date "2001-11-01" @default.
• W2146229087 modified "2023-10-16" @default.
• W2146229087 title "A facile and efficient method for the rearrangement of aryl-substituted epoxides to aldehydes and ketones using bismuth triflate" @default.
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• W2146229087 doi "https://doi.org/10.1016/s0040-4039(01)01519-2" @default.
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