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- W2166160988 abstract "The addition of dichlorocarbene to the double bond of 1-alkoxy-dihydrophosphole oxides and subsequent thermolysis of the adduct so obtained affords mixtures of the two double bond isomers of alkoxy-dihydrophosphinine oxides, if the latter step is carried out in the presence of triethylamine. Experimental data support the involvement of a cationic intermediate during the opening of the cyclopropane ring. A simplified procedure for the preparation of the starting dihydrophospholes is also presented." @default.
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- W2166160988 date "1990-10-01" @default.
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- W2166160988 title "Convenient synthesis of 1-alkoxy-1,2-dihydrophosphinine 1-oxides by ring enlargement" @default.
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- W2166160988 doi "https://doi.org/10.1002/hc.520010510" @default.
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