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- W2298591014 abstract "The concept of complementary semiconducting polymer blends (c-SPBs) for efficient charge transport was recently proposed and established by our group. In this study, we aim to reveal the influence of the length of conjugation-break spacers (CBSs) on charge transport properties of the matrix polymers and their corresponding complementary polymer blends. A series of 11 DPP-based semiconducting polymers DPP-Cm (m = 2–12) that incorporate CBSs of 2–12 methylene units along the polymer backbones were prepared and characterized. The UV–vis spectra and the ultraviolet photoelectron spectroscopy (UPS) measurements show that the CBS length has marginal influence on the polymer absorption spectra, energy levels, and band gaps. It also has little impact on polymer decomposition temperatures. However, the CBS length has a profound influence on polymer phase transition and the heat of fusion. As for the melt transitions, an odd–even effect is observed from DPP-C2 to DPP-C7, in which polymers with even-numbered CBSs sh..." @default.
- W2298591014 created "2016-06-24" @default.
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- W2298591014 date "2016-03-18" @default.
- W2298591014 modified "2023-10-18" @default.
- W2298591014 title "Complementary Semiconducting Polymer Blends: The Influence of Conjugation-Break Spacer Length in Matrix Polymers" @default.
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- W2298591014 doi "https://doi.org/10.1021/acs.macromol.6b00050" @default.
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