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- W2393659144 abstract "The urea combustion method was adopted to prepare proton conductor MCeO_3(M=Ca、 Sr、 Ba) precursor powders doped with Zr.From the XRD patterns and thermal analysis,600℃ is the reasonable calcination temperature for MCeO_3 to obtain fine powders with perovskite structure,which is stable in H_2S atmosphere under(700℃.) The solid electrolyte with 92% theory density are obtained after the powders were isostatically pressed at 200MPa and then sintered for 6h.The electromotive force(EMF) value of the steam concentration cell constructed by CaCe_(0.9-x)Zr_xY_(0.1)O_3,SrCe_(0.9-x)Zr_xY_(0.1)O_3,BaCe_(0.9-x) Zr_xY_(0.1)O_3(noted as CCZY、 SCZY、 BCZY,respectively) as solid electrolyte were measured on potentiostat.The magnitude order of EMF value is BCZYSCZYCCZY,EMF value increases with the increase of temperature,and keeps steady at above 700℃.At 500750℃,the biggest conductivity of BCZY reaches above 10~(-2) S/cm,while that of SCZY approaches 10~(-2) S/cm,which demonstrates that the two material are favorable for the reducing ohmic loss in the solid oxide fuel cell." @default.
- W2393659144 created "2016-06-24" @default.
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- W2393659144 date "2006-01-01" @default.
- W2393659144 modified "2023-09-23" @default.
- W2393659144 title "Preparation and characterization of proton-conducting solid electrolyte doped by Zr~(4+) and Y~(3+)" @default.
- W2393659144 hasPublicationYear "2006" @default.
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