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- W2397736561 abstract "The kinetics of the redox reaction between diphenylbenzidine (DPB) and thiosulfate was investigated in the range pH 2.0 to 4.5. Order of reaction with respect to thiosulfate, diphenylbenzidine and H + was found to be one.The following rate law is recommended : Rate = k 1 [DPB] [S 2 O 2 - 3 ] + k 2 K {DPB [H + ]) [S 2 O 2 - 3 ] where k 1 , k 2 are the rate constants for the reaction [DPB] + S 2 O 2 - 3 → [S 4 O 2 - 6 ] + product having the values of k 1 = 5.557 x 10 3 dm 3 mol - 1 s - 1 and k 2 = 5.827 x 10 8 dm 3 mol - 1 s - 1 K is the protonation constant of DPB having value of 476 dm3 mol - 1 ." @default.
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- W2397736561 date "2005-01-31" @default.
- W2397736561 modified "2023-10-16" @default.
- W2397736561 title "Kinetic study of redox reaction between diphenylbenzidine and thiosulfate" @default.
- W2397736561 doi "https://doi.org/10.5281/zenodo.5823872" @default.
- W2397736561 hasPublicationYear "2005" @default.
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