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- W2565114299 abstract "Abstract The optical and electronic properties of semiconducting materials are of great importance to a vast range of contemporary technologies. Diamond-cubic germanium is a well-known semiconductor, although other ‘exotic’ forms may possess distinct properties. In particular, there is currently no consensus for the band gap and electronic structure of ST12-Ge ( tP 12, P 4 3 2 1 2) due to experimental limitations in sample preparation and varying theoretical predictions. Here we report clear experimental and theoretical evidence for the intrinsic properties of ST12-Ge, including the first optical measurements on bulk samples. Phase-pure bulk samples of ST12-Ge were synthesized, and the structure and purity were verified using powder X-ray diffraction, transmission electron microscopy, Raman and wavelength/energy dispersive X-ray spectroscopy. Optical measurements indicate that ST12-Ge is a semiconductor with an indirect band gap of 0.59 eV and a direct optical transition at 0.74 eV, which is in good agreement with electrical transport measurements and our first-principles calculations." @default.
- W2565114299 created "2017-01-06" @default.
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- W2565114299 date "2017-01-03" @default.
- W2565114299 modified "2023-10-02" @default.
- W2565114299 title "Properties of the exotic metastable ST12 germanium allotrope" @default.
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- W2565114299 doi "https://doi.org/10.1038/ncomms13909" @default.
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