Matches in SemOpenAlex for { <https://semopenalex.org/work/W2609059670> ?p ?o ?g. }
- W2609059670 endingPage "127" @default.
- W2609059670 startingPage "118" @default.
- W2609059670 abstract "Abstract Iron based metal organic frameworks as novel catalysts were developed for ethylbenzene synthesis by alkylation of benzene with ethanol in low temperature gas phase conditions employing MIL-101 (Fe) and MIL-88 (Fe) catalysts. Both of catalysts were synthesized with solvothermal method. Catalysts characterization were performed using X-Ray Diffraction (XRD), Fourier Transform Infrared spectroscopy (FT-IR), Differential Scanning Calorimetry (DSC), and Field Emission Scanning Electron Microscope (FE-SEM). Nitrogen adsorption measurements were done to determining the catalyst surface area and pore volume and pore size distribution. Also the acidity of catalysts was measured using NH3-TPD. The catalysts activity and product selectivity for ethylbenzene production have been investigated in a specially designed flow microreactor in gas phase. Effects of temperature and space velocity at constant benzene to ethanol ratio (3:1 volumetric ratio) have been studied for catalyst performance and ethylbenzene selectivity and yield. In comparison of two synthesized catalysts, MIL-88 showed a higher performance (100% ethanol conversion, 72% benzene conversion and 76% ethylbenzene selectivity at 175 °C). The main byproduct was recognized as toluene. Long reaction time for both catalysts showed no decline in conversion and selectivity of desired product. The BET measurement and the FTIR spectra of used catalysts revealed these Fe-based metal organic frameworks are stable catalysts for alkylation of benzene by ethanol." @default.
- W2609059670 created "2017-05-05" @default.
- W2609059670 creator A5007432472 @default.
- W2609059670 creator A5075698243 @default.
- W2609059670 date "2017-09-01" @default.
- W2609059670 modified "2023-09-26" @default.
- W2609059670 title "Alkylation of benzene over Fe-based metal organic frameworks (MOFs) at low temperature condition" @default.
- W2609059670 cites W1907925021 @default.
- W2609059670 cites W1968264573 @default.
- W2609059670 cites W1977833019 @default.
- W2609059670 cites W1979681627 @default.
- W2609059670 cites W2000838456 @default.
- W2609059670 cites W2002319969 @default.
- W2609059670 cites W2017430809 @default.
- W2609059670 cites W2019650129 @default.
- W2609059670 cites W2022192238 @default.
- W2609059670 cites W2023059522 @default.
- W2609059670 cites W2030489223 @default.
- W2609059670 cites W2033275508 @default.
- W2609059670 cites W2034984769 @default.
- W2609059670 cites W2035324574 @default.
- W2609059670 cites W2044200191 @default.
- W2609059670 cites W2047103832 @default.
- W2609059670 cites W2053292178 @default.
- W2609059670 cites W2054095047 @default.
- W2609059670 cites W2056127514 @default.
- W2609059670 cites W2058341826 @default.
- W2609059670 cites W2058446303 @default.
- W2609059670 cites W2062566809 @default.
- W2609059670 cites W2067988641 @default.
- W2609059670 cites W2075629163 @default.
- W2609059670 cites W2078504463 @default.
- W2609059670 cites W2079585214 @default.
- W2609059670 cites W2082952862 @default.
- W2609059670 cites W2084607306 @default.
- W2609059670 cites W2123484582 @default.
- W2609059670 cites W2142699453 @default.
- W2609059670 cites W2146762189 @default.
- W2609059670 cites W2170749193 @default.
- W2609059670 cites W2227569474 @default.
- W2609059670 cites W2230516219 @default.
- W2609059670 cites W2409741477 @default.
- W2609059670 cites W2460506170 @default.
- W2609059670 cites W2461144453 @default.
- W2609059670 cites W2558447226 @default.
- W2609059670 doi "https://doi.org/10.1016/j.micromeso.2017.04.058" @default.
- W2609059670 hasPublicationYear "2017" @default.
- W2609059670 type Work @default.
- W2609059670 sameAs 2609059670 @default.
- W2609059670 citedByCount "31" @default.
- W2609059670 countsByYear W26090596702017 @default.
- W2609059670 countsByYear W26090596702018 @default.
- W2609059670 countsByYear W26090596702019 @default.
- W2609059670 countsByYear W26090596702020 @default.
- W2609059670 countsByYear W26090596702021 @default.
- W2609059670 countsByYear W26090596702022 @default.
- W2609059670 countsByYear W26090596702023 @default.
- W2609059670 crossrefType "journal-article" @default.
- W2609059670 hasAuthorship W2609059670A5007432472 @default.
- W2609059670 hasAuthorship W2609059670A5075698243 @default.
- W2609059670 hasConcept C127413603 @default.
- W2609059670 hasConcept C150394285 @default.
- W2609059670 hasConcept C161790260 @default.
- W2609059670 hasConcept C164361826 @default.
- W2609059670 hasConcept C178790620 @default.
- W2609059670 hasConcept C179104552 @default.
- W2609059670 hasConcept C179366358 @default.
- W2609059670 hasConcept C185592680 @default.
- W2609059670 hasConcept C192562407 @default.
- W2609059670 hasConcept C2777691172 @default.
- W2609059670 hasConcept C42360764 @default.
- W2609059670 hasConcept C544153396 @default.
- W2609059670 hasConceptScore W2609059670C127413603 @default.
- W2609059670 hasConceptScore W2609059670C150394285 @default.
- W2609059670 hasConceptScore W2609059670C161790260 @default.
- W2609059670 hasConceptScore W2609059670C164361826 @default.
- W2609059670 hasConceptScore W2609059670C178790620 @default.
- W2609059670 hasConceptScore W2609059670C179104552 @default.
- W2609059670 hasConceptScore W2609059670C179366358 @default.
- W2609059670 hasConceptScore W2609059670C185592680 @default.
- W2609059670 hasConceptScore W2609059670C192562407 @default.
- W2609059670 hasConceptScore W2609059670C2777691172 @default.
- W2609059670 hasConceptScore W2609059670C42360764 @default.
- W2609059670 hasConceptScore W2609059670C544153396 @default.
- W2609059670 hasFunder F4320322671 @default.
- W2609059670 hasLocation W26090596701 @default.
- W2609059670 hasOpenAccess W2609059670 @default.
- W2609059670 hasPrimaryLocation W26090596701 @default.
- W2609059670 hasRelatedWork W2064564370 @default.
- W2609059670 hasRelatedWork W2317360025 @default.
- W2609059670 hasRelatedWork W2748952813 @default.
- W2609059670 hasRelatedWork W2775325911 @default.
- W2609059670 hasRelatedWork W2899084033 @default.
- W2609059670 hasRelatedWork W2949668585 @default.
- W2609059670 hasRelatedWork W2951550788 @default.
- W2609059670 hasRelatedWork W2952237696 @default.
- W2609059670 hasRelatedWork W2952540179 @default.
- W2609059670 hasRelatedWork W2953018743 @default.