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- W265697659 abstract "Sulfuric and aerated solutions of peroxyvanadic ions containing nonperoxided pentavalent vanadium were irradiated by Co/sup 60/ gamma rays. The reduction yields of either ionic species was dependent on their relative concentrations, while the total reduction yield of tetrayalent vanadium is independent of it (G/sub VO2+ = 6.5). The quantitative interpretation of the results was made by adopting the same hypothesis which was necessary to explain the reduction of nonperoxided V/sup 5+/ ions alone (J. chim. phys. 54, 659(1957)). Moreover, two chemical reactions should be considered in the chemical calculations: the catalytic decomposition of peroxyvanadic ions in the presence of tetravalent vanadium and the oxidation of the tetravalent ions by oxygenated water. (tr-auth)" @default.
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- W265697659 date "1958-10-01" @default.
- W265697659 modified "2023-09-23" @default.
- W265697659 title "CHEMICAL EFFECTS OF IONIZING RADIATIONS ON AQUEOUS SOLUTIONS OF VANADIUM. II. REDUCTION BY $gamma$ RAYS OF THE PEROXYVANADIC ION IN ACID MEDIA" @default.
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