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- W2747143015 abstract "An investigation of carbodicarbenes, the less explored member of the carbenic complex/ligand family has yielded unexpected electronic features and concomitant reactivity. Observed 1,2-addition of E-H bonds (E = B, C, Si) across the carbone central carbon and that of the flanking N-heterocyclic carbene (NHC) fragment, combined with single-crystal X-ray studies of a model Pd complex strongly suggests a significant level of π-accepting ability at the central carbon of the NHC moiety. This feature is atypical of classic NHCs, which are strong σ-donors, with only nominal π-accepting ability. The unanticipated π-acidity is critical for engendering carbodicarbenes with reactivity more commonly observed with frustrated Lewis pairs (FLPs) rather than the more closely related NHCs and cyclic (alkyl)(amino)carbenes (CAACs)." @default.
- W2747143015 created "2017-08-31" @default.
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- W2747143015 date "2017-08-30" @default.
- W2747143015 modified "2023-10-16" @default.
- W2747143015 title "Carbodicarbenes: Unexpected π-Accepting Ability during Reactivity with Small Molecules" @default.
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- W2747143015 cites W1897198241 @default.
- W2747143015 cites W1967888944 @default.
- W2747143015 cites W1968267262 @default.
- W2747143015 cites W1970979049 @default.
- W2747143015 cites W1974931722 @default.
- W2747143015 cites W1982567581 @default.
- W2747143015 cites W1986695985 @default.
- W2747143015 cites W1988716453 @default.
- W2747143015 cites W1990546479 @default.
- W2747143015 cites W1994229205 @default.
- W2747143015 cites W1996871889 @default.
- W2747143015 cites W2000154177 @default.
- W2747143015 cites W2002629749 @default.
- W2747143015 cites W2003486164 @default.
- W2747143015 cites W2003555872 @default.
- W2747143015 cites W2005227604 @default.
- W2747143015 cites W2010940830 @default.
- W2747143015 cites W2012874582 @default.
- W2747143015 cites W2018702845 @default.
- W2747143015 cites W2021200484 @default.
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- W2747143015 cites W2082239003 @default.
- W2747143015 cites W2085337369 @default.
- W2747143015 cites W2092667780 @default.
- W2747143015 cites W2093965406 @default.
- W2747143015 cites W2097615292 @default.
- W2747143015 cites W2103660943 @default.
- W2747143015 cites W2108132042 @default.
- W2747143015 cites W2109726612 @default.
- W2747143015 cites W2120552820 @default.
- W2747143015 cites W2123370558 @default.
- W2747143015 cites W2127265726 @default.
- W2747143015 cites W2134897831 @default.
- W2747143015 cites W2140141423 @default.
- W2747143015 cites W2142839187 @default.
- W2747143015 cites W2143453620 @default.
- W2747143015 cites W2149661779 @default.
- W2747143015 cites W2151515896 @default.
- W2747143015 cites W2151640189 @default.
- W2747143015 cites W2152561290 @default.
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- W2747143015 cites W2154029669 @default.
- W2747143015 cites W2156583367 @default.
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- W2747143015 cites W2160057981 @default.
- W2747143015 cites W2161384163 @default.
- W2747143015 cites W2164714240 @default.
- W2747143015 cites W2313547028 @default.
- W2747143015 cites W2318129697 @default.
- W2747143015 cites W2325339364 @default.
- W2747143015 cites W2325951170 @default.
- W2747143015 cites W2326418570 @default.
- W2747143015 cites W2327754372 @default.
- W2747143015 cites W2328100592 @default.
- W2747143015 cites W2329328619 @default.
- W2747143015 cites W2330222529 @default.
- W2747143015 cites W2335068770 @default.
- W2747143015 cites W2461115261 @default.
- W2747143015 cites W2550883682 @default.
- W2747143015 cites W2604156473 @default.
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- W2747143015 doi "https://doi.org/10.1021/jacs.7b08031" @default.
- W2747143015 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28813602" @default.
- W2747143015 hasPublicationYear "2017" @default.
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