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- W2895650235 abstract "Abstract The oxidation of carbon monoxide (CO) over PdRu solid solution nanoparticles was studied by the combined theoretical and experimental approaches. In this work, CO and O adsorptions on PdRu alloy surface models were theoretically investigated to understand the kinetics of CO oxidation reaction. It was found that CO adsorption on Pd atom in the PdRu alloy surfaces is weaker than on monometallic surfaces. From the experiment, reaction order of CO on the PdRu surface was observed to be smaller than that on Pd surface. While, the positive first order with respect to O2 obtained for both Pd and PdRu alloy surfaces. Catalytic reaction mechanism is discussed on the basis of both theoretical and experimental observations." @default.
- W2895650235 created "2018-10-12" @default.
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- W2895650235 date "2018-11-01" @default.
- W2895650235 modified "2023-10-14" @default.
- W2895650235 title "Combined theoretical and experimental studies of CO oxidation on PdRu nanoalloys" @default.
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- W2895650235 doi "https://doi.org/10.1016/j.apcata.2018.10.002" @default.
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