FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2903973810> ?p ?o ?g. }

• W2903973810 endingPage "1038" @default.
• W2903973810 startingPage "1030" @default.
• W2903973810 abstract "Derivatisation of Grignard synthons “PhAeI(thf) n ” (Ae = Mg‐Ba) prepared in situ from reactions of metal filings and iodobenzene provides a one‐pot synthesis of heteroleptic N donor alkaline earth iodide complexes. Protolysis of “PhAeI(thf) n ” with 3,5‐diphenylpyrazole (Ph 2 pzH) yields pyrazolate complexes [Mg 2 (µ‐Ph 2 pz) 2 (I) 2 (thf) 3 ] ( 1 ), [Ae(Ph 2 pz)(I)(thf) 4 ] (Ae = Ca ( 2 ), Sr ( 3 )), and [Ba 2 (Ph 2 pz) 2 (µ‐I) 2 (thf) 8 ] ( 4 ). Addition of the Ae‐Ph moiety to carbodiimide MesN=C=NMes (Mes = 2,4,6‐(CH 3 ) 3 C 6 H 2 ) gave a series of benzamidinate iodide complexes [Ca 2 {(MesN) 2 CPh} 2 (µ‐I) 2 (thf) 4 ] ( 6) , [Sr{(MesN) 2 CPh}(I)(thf) 4 ] ( 7 ), and [{Ba{(MesN) 2 CPh}(µ‐I)(thf) 3 } ∞ ] ( 8 ). By contrast a symmetrical magnesium complex [Mg{(MesN) 2 CPh} 2 (thf)] ( 5 ) was obtained by Schlenk redistribution. These syntheses proceed without pre‐activation of the metal for strontium and barium, and after activation with 2 mol‐% iodine for calcium. The heavy alkaline earth metal complexes are the first examples of heteroleptic halide pyrazolate or amidinate complexes for strontium and barium. Complexes 1 , 3 , 4 and 6–8 were characterised crystallographically, revealing diverse structural chemistry of heteroleptic amidinate and pyrazolate iodide complexes across the alkaline earth series. A highlight is [Ba{(MesN) 2 CPh}(µ‐I)(thf) 3 ] ∞ ( 8 ) – an iodide bridged infinite 1‐D polymer." @default.
• W2903973810 created "2018-12-22" @default.
• W2903973810 creator A5003309718 @default.
• W2903973810 creator A5061740134 @default.
• W2903973810 creator A5064617775 @default.
• W2903973810 creator A5065584824 @default.
• W2903973810 creator A5070036826 @default.
• W2903973810 date "2019-01-18" @default.
• W2903973810 modified "2023-09-30" @default.
• W2903973810 title "Functionalised Alkaline Earth Iodides from Grignard Synthons “PhAeI(thf)<i>_n</i>” (Ae = Mg‐Ba)" @default.
• W2903973810 cites W1589176476 @default.
• W2903973810 cites W1812295435 @default.
• W2903973810 cites W1878519161 @default.
• W2903973810 cites W1896434597 @default.
• W2903973810 cites W1965047402 @default.
• W2903973810 cites W1972403785 @default.
• W2903973810 cites W1978712974 @default.
• W2903973810 cites W1980541184 @default.
• W2903973810 cites W1981825949 @default.
• W2903973810 cites W1984729923 @default.
• W2903973810 cites W1985693499 @default.
• W2903973810 cites W1987582187 @default.
• W2903973810 cites W1990147235 @default.
• W2903973810 cites W1994287725 @default.
• W2903973810 cites W2000840258 @default.
• W2903973810 cites W2009872680 @default.
• W2903973810 cites W2010772954 @default.
• W2903973810 cites W2010885975 @default.
• W2903973810 cites W2012064758 @default.
• W2903973810 cites W2012103478 @default.
• W2903973810 cites W2012433173 @default.
• W2903973810 cites W2017166463 @default.
• W2903973810 cites W2025296813 @default.
• W2903973810 cites W2029450641 @default.
• W2903973810 cites W2031238764 @default.
• W2903973810 cites W2035182085 @default.
• W2903973810 cites W2043722296 @default.
• W2903973810 cites W2052394523 @default.
• W2903973810 cites W2053491719 @default.
• W2903973810 cites W2055802618 @default.
• W2903973810 cites W2057372713 @default.
• W2903973810 cites W2057659955 @default.
• W2903973810 cites W2067933018 @default.
• W2903973810 cites W2069625710 @default.
• W2903973810 cites W2069993024 @default.
• W2903973810 cites W2073052334 @default.
• W2903973810 cites W2077270453 @default.
• W2903973810 cites W2082344108 @default.
• W2903973810 cites W2083569452 @default.
• W2903973810 cites W2086553486 @default.
• W2903973810 cites W2088619261 @default.
• W2903973810 cites W2089832792 @default.
• W2903973810 cites W2093289023 @default.
• W2903973810 cites W2094947909 @default.
• W2903973810 cites W2101258722 @default.
• W2903973810 cites W2105249240 @default.
• W2903973810 cites W2109391586 @default.
• W2903973810 cites W2110035145 @default.
• W2903973810 cites W2125132077 @default.
• W2903973810 cites W2125680384 @default.
• W2903973810 cites W2125810639 @default.
• W2903973810 cites W2131350133 @default.
• W2903973810 cites W2137942211 @default.
• W2903973810 cites W2142537644 @default.
• W2903973810 cites W2142906788 @default.
• W2903973810 cites W2152709093 @default.
• W2903973810 cites W2153430465 @default.
• W2903973810 cites W2167590372 @default.
• W2903973810 cites W2202578477 @default.
• W2903973810 cites W2277021315 @default.
• W2903973810 cites W2313502442 @default.
• W2903973810 cites W2315975535 @default.
• W2903973810 cites W2461358631 @default.
• W2903973810 cites W2465878351 @default.
• W2903973810 cites W2473131502 @default.
• W2903973810 cites W2477861610 @default.
• W2903973810 cites W2481328376 @default.
• W2903973810 cites W2523412801 @default.
• W2903973810 cites W2562706900 @default.
• W2903973810 cites W2600421651 @default.
• W2903973810 cites W2742991421 @default.
• W2903973810 cites W2751791143 @default.
• W2903973810 cites W2752210947 @default.
• W2903973810 cites W2760088752 @default.
• W2903973810 cites W2765389498 @default.
• W2903973810 cites W2773967455 @default.
• W2903973810 cites W2782151160 @default.
• W2903973810 cites W2799940310 @default.
• W2903973810 cites W2810425178 @default.
• W2903973810 cites W2886187568 @default.
• W2903973810 cites W2949817936 @default.
• W2903973810 cites W4240754979 @default.
• W2903973810 cites W4243365592 @default.
• W2903973810 cites W4254978549 @default.
• W2903973810 cites W49741751 @default.
• W2903973810 doi "https://doi.org/10.1002/ejic.201801489" @default.
• W2903973810 hasPublicationYear "2019" @default.
• W2903973810 type Work @default.

• next