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- W2906498426 abstract "The synthesis of the first photoinitiator (PI) based on thioxanthone (TX) with 1,6-heptadiene structure is described. This PI (TXdMA) absorbs in the near UV–vis region (435–439 nm; with absorption redshift≈50 nm and ε values comparable to TX). Photopolymerization results demonstrate that although TXdMA is not an effective one-component polymerizable photoinitiator, it can successfully initiate photopolymerization of poly(ethylene glycol) diacrylate (PEGDA, Mn = 250 D) and trimethylolpropane triacrylate (TMPTA) in the presence of bis-(4-tert-butylphenyl)-iodonium hexafluorophosphate (Iod) similar to TX/Iod. TXdMA exhibits better migration stability than TX. Absorption, fluorescence, steady state photolysis and cyclic voltammetry experiments are carried out to investigate the photochemical mechanisms." @default.
- W2906498426 created "2019-01-01" @default.
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- W2906498426 date "2019-03-01" @default.
- W2906498426 modified "2023-10-03" @default.
- W2906498426 title "Thioxanthone-functionalized 1,6-heptadiene as monomeric photoinitiator" @default.
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- W2906498426 doi "https://doi.org/10.1016/j.porgcoat.2018.12.014" @default.
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