Matches in SemOpenAlex for { <https://semopenalex.org/work/W2914111424> ?p ?o ?g. }
- W2914111424 endingPage "407" @default.
- W2914111424 startingPage "398" @default.
- W2914111424 abstract "Abstract We present an experimental study combined with first-principle methods and the chemical approach to characterize NiO surfaces. The comparison of two simulated surfaces, the apolar (100) and the polar (111) surfaces, allows to better differentiate their reactivity and their electronic properties. The redox chemistry upon the adsorption of different gases such as H2 and H2O on pure and defective surfaces is also considered. The synthesized NiO nanoparticles obtained from triethylamine have plate-like morphologies with a crystalline size of 11 nm and the (111) surface, being the basal plane. This dominant surface is the most reactive one, it is hydroxylated at room conditions. Theoretical results confirm that the (111) surface is also likely to be hydroxylated under catalytic conditions for alkane oxidative dehydrogenation (ODH). The (001) surface at the opposite does not adsorb H2 and is dehydroxylated. This apolar surface is not expected to be reactive. The results enable an interpretation of the high reactivity of the catalyst regarding morphological data provided by SEM (scanning electron microscopy) and HRTEM (high resolution transmission electron microscopy)." @default.
- W2914111424 created "2019-02-21" @default.
- W2914111424 creator A5026198665 @default.
- W2914111424 creator A5037160761 @default.
- W2914111424 creator A5044051503 @default.
- W2914111424 creator A5077647084 @default.
- W2914111424 date "2019-06-01" @default.
- W2914111424 modified "2023-09-25" @default.
- W2914111424 title "A theoretical and experimental study of the NiO nanocatalyst reactivity" @default.
- W2914111424 cites W1491200236 @default.
- W2914111424 cites W1646770854 @default.
- W2914111424 cites W1964734263 @default.
- W2914111424 cites W1966156734 @default.
- W2914111424 cites W1967093199 @default.
- W2914111424 cites W1973228765 @default.
- W2914111424 cites W1974731737 @default.
- W2914111424 cites W1975071145 @default.
- W2914111424 cites W1975656408 @default.
- W2914111424 cites W1979221007 @default.
- W2914111424 cites W1979544533 @default.
- W2914111424 cites W1980001854 @default.
- W2914111424 cites W1985882365 @default.
- W2914111424 cites W1991716691 @default.
- W2914111424 cites W1994035711 @default.
- W2914111424 cites W1994127857 @default.
- W2914111424 cites W1997899598 @default.
- W2914111424 cites W2005272188 @default.
- W2914111424 cites W2007395042 @default.
- W2914111424 cites W2007868549 @default.
- W2914111424 cites W2008796388 @default.
- W2914111424 cites W2013202432 @default.
- W2914111424 cites W2013268772 @default.
- W2914111424 cites W2013710686 @default.
- W2914111424 cites W2015102488 @default.
- W2914111424 cites W2022085321 @default.
- W2914111424 cites W2024683261 @default.
- W2914111424 cites W2026448881 @default.
- W2914111424 cites W2034019090 @default.
- W2914111424 cites W2036926759 @default.
- W2914111424 cites W2047482324 @default.
- W2914111424 cites W2049079467 @default.
- W2914111424 cites W2049918134 @default.
- W2914111424 cites W2050417506 @default.
- W2914111424 cites W2050780685 @default.
- W2914111424 cites W2053395703 @default.
- W2914111424 cites W2060246466 @default.
- W2914111424 cites W2060968334 @default.
- W2914111424 cites W2061669804 @default.
- W2914111424 cites W2065798107 @default.
- W2914111424 cites W2068336431 @default.
- W2914111424 cites W2070589820 @default.
- W2914111424 cites W2072234614 @default.
- W2914111424 cites W2074604759 @default.
- W2914111424 cites W2075615349 @default.
- W2914111424 cites W2076312689 @default.
- W2914111424 cites W2080293670 @default.
- W2914111424 cites W2080420893 @default.
- W2914111424 cites W2081957072 @default.
- W2914111424 cites W2081988927 @default.
- W2914111424 cites W2083927719 @default.
- W2914111424 cites W2087302072 @default.
- W2914111424 cites W2087698390 @default.
- W2914111424 cites W2089442860 @default.
- W2914111424 cites W2089638549 @default.
- W2914111424 cites W2090614701 @default.
- W2914111424 cites W2092923870 @default.
- W2914111424 cites W2094695189 @default.
- W2914111424 cites W2095232930 @default.
- W2914111424 cites W2165995594 @default.
- W2914111424 cites W2167590372 @default.
- W2914111424 cites W2326213926 @default.
- W2914111424 cites W2329717581 @default.
- W2914111424 cites W2333598814 @default.
- W2914111424 cites W233910529 @default.
- W2914111424 cites W2522203689 @default.
- W2914111424 cites W2765595043 @default.
- W2914111424 cites W2783628557 @default.
- W2914111424 cites W2900788237 @default.
- W2914111424 cites W2949263855 @default.
- W2914111424 cites W2972261791 @default.
- W2914111424 cites W4244733673 @default.
- W2914111424 doi "https://doi.org/10.1016/j.apsusc.2019.01.253" @default.
- W2914111424 hasPublicationYear "2019" @default.
- W2914111424 type Work @default.
- W2914111424 sameAs 2914111424 @default.
- W2914111424 citedByCount "8" @default.
- W2914111424 countsByYear W29141114242019 @default.
- W2914111424 countsByYear W29141114242020 @default.
- W2914111424 countsByYear W29141114242021 @default.
- W2914111424 countsByYear W29141114242022 @default.
- W2914111424 countsByYear W29141114242023 @default.
- W2914111424 crossrefType "journal-article" @default.
- W2914111424 hasAuthorship W2914111424A5026198665 @default.
- W2914111424 hasAuthorship W2914111424A5037160761 @default.
- W2914111424 hasAuthorship W2914111424A5044051503 @default.
- W2914111424 hasAuthorship W2914111424A5077647084 @default.
- W2914111424 hasConcept C142724271 @default.
- W2914111424 hasConcept C161790260 @default.