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- W2944147023 abstract "A Ni/NiO catalyst is reported for converting a phenolic compound, such as guaiacol, and cashew nut shell liquid (CNSL) into different hydrocarbons. High guaiacol conversion (80%) and higher cyclohexane selectivity (23%) over the Ni/NiO catalyst are reported in comparison to the other reported Ni-based catalysts at a temperature of 300 °C and 50 bar H2 pressure. The CNSL hydrodeoxygenation (HDO) activity increased with the temperature and reached a maximum conversion (100%) at 300 °C. The high total acidic sites of Ni/NiO favored the high conversion (100%) with 15% cyclohexane selectivity, 30% phenol selectivity, and maximum selectivity for tetradecane (45%) in CNSL HDO. This is the first such report to the best of our knowledge. The Ni/NiO catalyst was characterized by X-ray diffraction (XRD), transmission electron microscopy, X-ray photoelectron spectroscopy, temperature-programmed desorption of ammonia, N2 sorption, X-ray absorption near edge structure, and X-ray absorption fine structure (XAFS). The products were analyzed by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, gas chromatography, and gas chromatography–mass spectrometry. XRD analysis showed that NiO crystallinity decreased while Ni crystallinity increased after reduction. XAFS analysis confirmed that the metallic Ni nature increased after reduction, as indicated by a decrease in the Ni–Ni1Ni bond distance from 2.596 Å for unreduced Ni/NiO to 2.519 Å (closer to that for the metallic Ni face-centered cubic phase) for the reduced sample, which would result in improved hydrogenation activity of the reduced catalyst. The spent Ni/NiO catalyst showed good stability without any phase change during the reaction and retained its original structure." @default.
- W2944147023 created "2019-05-16" @default.
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- W2944147023 date "2019-05-09" @default.
- W2944147023 modified "2023-09-26" @default.
- W2944147023 title "Magnetically Recoverable Ni/NiO Catalyst for Hydrogenation of Cashew Nut Shell Oil to Value-Added Products" @default.
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- W2944147023 doi "https://doi.org/10.1021/acs.energyfuels.9b00663" @default.
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