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- W2949602600 abstract "Abstract Deprotonation of N ‐protected esters of the amino acids alanine 1 , ethylglycin 6 , valine 7 , and phenylalanine 8 with LDA and subsequent addition of various metal salts result in the formation of a probably chelated metal enolate. Aldol reactions of these enolates with aldehydes afford the anti isomers of α‐alkylated α‐amino‐β‐hydroxy acids in a highly diastereoselective fashion. Best results are obtained with titanium enolates, bulky aliphatic aldehydes, and sterically demanding amino acids." @default.
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- W2949602600 date "1996-07-01" @default.
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- W2949602600 title "<i>anti</i>‐Selective Aldol Reactions of Amino Acid Ester Enolates. Application to the Synthesis of α‐Alkylated β‐Hydroxy Amino Acids" @default.
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- W2949602600 doi "https://doi.org/10.1002/jlac.199619960713" @default.
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