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- W2951268923 abstract "The first catalytic α-alkylation reaction of benzyl sulfides and 1,3-dithianes with styrenes and conjugated dienes was developed under mild conditions by using a readily available Brønsted base potassium bis(trimethylsilyl)amide (KHMDS) as catalyst. The reaction displayed good functional group tolerance, high efficiency, and excellent chemoselectivity. A series of desired alkylation products were obtained in good to high yield. Preliminary mechanism studies suggested that two of the potassium amide catalyst molecules worked together in the catalytic cycle." @default.
- W2951268923 created "2019-06-27" @default.
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- W2951268923 date "2019-06-20" @default.
- W2951268923 modified "2023-10-15" @default.
- W2951268923 title "Dimeric Potassium Amide-Catalyzed α-Alkylation of Benzyl Sulfides and 1,3-Dithianes" @default.
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- W2951268923 doi "https://doi.org/10.1021/acs.orglett.9b01994" @default.
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