Matches in SemOpenAlex for { <https://semopenalex.org/work/W2953291619> ?p ?o ?g. }
- W2953291619 abstract "Abstract Regulation of crystalline micelles is difficult to achieve because of the strong solidification of crystallization. In this present work, an amphiphilic triblock copolymer poly(ethylene oxide)‐ b ‐poly(ε‐caprolactone)‐ b ‐poly(4‐vinylpyridine) (PEO‐ b ‐PCL‐ b ‐P4VP) is prepared, in which the P4VP block serves as an H‐bonding acceptor. It is originally self‐assembled into crystalline lamellar micelles in aqueous solution. Subsequently, the effect of varying pH and organic diacids on morphological transition is investigated in detail. Lamellae‐to‐cylinder‐to‐sphere transitions are observed after decreasing the pH or with the addition of organic diacids with different chain spacers. The decreasing pH causes increasing hydrophilicity of the P4VP block, while adding organic diacids results in an increasing corona swelling of the P4VP segment, both of which lead to a decreasing crystallinity of the poly(ε‐caprolactone) core. Consequently, morphological variety changing from lamellar to worm‐like to spherical micelles can be achieved." @default.
- W2953291619 created "2019-06-27" @default.
- W2953291619 creator A5024010704 @default.
- W2953291619 creator A5043431883 @default.
- W2953291619 creator A5045066392 @default.
- W2953291619 creator A5056933414 @default.
- W2953291619 creator A5059419815 @default.
- W2953291619 creator A5069494787 @default.
- W2953291619 creator A5086161254 @default.
- W2953291619 date "2019-06-12" @default.
- W2953291619 modified "2023-09-27" @default.
- W2953291619 title "Disassembly of Crystalline Platelets of an Amphiphilic Triblock Copolymer Mediated by Varying pH and Organic Diacids" @default.
- W2953291619 cites W1968480115 @default.
- W2953291619 cites W1973533066 @default.
- W2953291619 cites W1978985250 @default.
- W2953291619 cites W1980486141 @default.
- W2953291619 cites W1985921111 @default.
- W2953291619 cites W1990232537 @default.
- W2953291619 cites W1990611345 @default.
- W2953291619 cites W1991604237 @default.
- W2953291619 cites W1993001848 @default.
- W2953291619 cites W1995751631 @default.
- W2953291619 cites W2001583230 @default.
- W2953291619 cites W2005139687 @default.
- W2953291619 cites W2010472509 @default.
- W2953291619 cites W2013660423 @default.
- W2953291619 cites W2016898914 @default.
- W2953291619 cites W2023435894 @default.
- W2953291619 cites W2025448720 @default.
- W2953291619 cites W2026100316 @default.
- W2953291619 cites W2026653166 @default.
- W2953291619 cites W2028446490 @default.
- W2953291619 cites W2030676382 @default.
- W2953291619 cites W2032971865 @default.
- W2953291619 cites W2037447559 @default.
- W2953291619 cites W2041139744 @default.
- W2953291619 cites W2046946511 @default.
- W2953291619 cites W2057954035 @default.
- W2953291619 cites W2062258474 @default.
- W2953291619 cites W2065514180 @default.
- W2953291619 cites W2067886617 @default.
- W2953291619 cites W2071049040 @default.
- W2953291619 cites W2083612730 @default.
- W2953291619 cites W2089436321 @default.
- W2953291619 cites W2097572311 @default.
- W2953291619 cites W2131894264 @default.
- W2953291619 cites W2135886130 @default.
- W2953291619 cites W2137630378 @default.
- W2953291619 cites W2150690527 @default.
- W2953291619 cites W2163645866 @default.
- W2953291619 cites W2282039065 @default.
- W2953291619 cites W2312986878 @default.
- W2953291619 cites W2313072904 @default.
- W2953291619 cites W2315000157 @default.
- W2953291619 cites W2318094045 @default.
- W2953291619 cites W2327627536 @default.
- W2953291619 cites W2330071145 @default.
- W2953291619 cites W2410875739 @default.
- W2953291619 cites W2439268522 @default.
- W2953291619 cites W2469923014 @default.
- W2953291619 cites W2481125053 @default.
- W2953291619 cites W2559903941 @default.
- W2953291619 cites W2569144646 @default.
- W2953291619 cites W2589017647 @default.
- W2953291619 cites W2602938718 @default.
- W2953291619 cites W2605521873 @default.
- W2953291619 cites W2618977188 @default.
- W2953291619 cites W2750027892 @default.
- W2953291619 cites W2765748477 @default.
- W2953291619 cites W2789048350 @default.
- W2953291619 cites W2886458509 @default.
- W2953291619 cites W2892189515 @default.
- W2953291619 cites W2907003097 @default.
- W2953291619 cites W2908954095 @default.
- W2953291619 cites W4248781089 @default.
- W2953291619 doi "https://doi.org/10.1002/macp.201900187" @default.
- W2953291619 hasPublicationYear "2019" @default.
- W2953291619 type Work @default.
- W2953291619 sameAs 2953291619 @default.
- W2953291619 citedByCount "2" @default.
- W2953291619 countsByYear W29532916192020 @default.
- W2953291619 crossrefType "journal-article" @default.
- W2953291619 hasAuthorship W2953291619A5024010704 @default.
- W2953291619 hasAuthorship W2953291619A5043431883 @default.
- W2953291619 hasAuthorship W2953291619A5045066392 @default.
- W2953291619 hasAuthorship W2953291619A5056933414 @default.
- W2953291619 hasAuthorship W2953291619A5059419815 @default.
- W2953291619 hasAuthorship W2953291619A5069494787 @default.
- W2953291619 hasAuthorship W2953291619A5086161254 @default.
- W2953291619 hasConcept C11268172 @default.
- W2953291619 hasConcept C127413603 @default.
- W2953291619 hasConcept C15920480 @default.
- W2953291619 hasConcept C159985019 @default.
- W2953291619 hasConcept C178790620 @default.
- W2953291619 hasConcept C184651966 @default.
- W2953291619 hasConcept C185592680 @default.
- W2953291619 hasConcept C188027245 @default.
- W2953291619 hasConcept C192562407 @default.
- W2953291619 hasConcept C203036418 @default.
- W2953291619 hasConcept C2777801237 @default.