Matches in SemOpenAlex for { <https://semopenalex.org/work/W2994830143> ?p ?o ?g. }
- W2994830143 endingPage "1096" @default.
- W2994830143 startingPage "1087" @default.
- W2994830143 abstract "Cyanoformamides are prevalent as versatile building blocks for accessing synthetically useful intermediates and biologically active compounds. The development of a milder, simpler, and more efficient approach to cyanoformamides is nontrivial. Herein, we demonstrate the effectiveness of 4,5-dioxo-imidazolinium cation activation for transforming 1-acyl-1-carbamoyl oximes to cyanoformamides. By making use of the readily available and highly modifiable dichloroimidazolidinediones (DCIDs), this novel method of activation offers reactivity remarkably greater than that of other reported protocols, exhibits a high functional group compatibility with mild conditions, and could be scaled up easily. More than 30 examples are demonstrated with good to excellent yields in short reaction times. This research not only provides a mild and efficient alternative approach to assembling a portfolio of cyanoformamides but also extends the dichloroimidazolidinedione-mediated chemistry to encompass the C–C bond cleavage reaction." @default.
- W2994830143 created "2019-12-26" @default.
- W2994830143 creator A5006528597 @default.
- W2994830143 creator A5020803502 @default.
- W2994830143 creator A5027792053 @default.
- W2994830143 creator A5029400180 @default.
- W2994830143 creator A5067010720 @default.
- W2994830143 creator A5077367725 @default.
- W2994830143 creator A5082704360 @default.
- W2994830143 creator A5090815103 @default.
- W2994830143 creator A5091103434 @default.
- W2994830143 date "2019-12-17" @default.
- W2994830143 modified "2023-10-05" @default.
- W2994830143 title "4,5-Dioxo-imidazolinium Cation Activation of 1-Acyl-1-carbamoyl Oximes: Access to Cyanoformamides Using Dichloroimidazolidinedione" @default.
- W2994830143 cites W1963709796 @default.
- W2994830143 cites W1964420716 @default.
- W2994830143 cites W1965103834 @default.
- W2994830143 cites W1979595154 @default.
- W2994830143 cites W1981462628 @default.
- W2994830143 cites W2004523222 @default.
- W2994830143 cites W2013253617 @default.
- W2994830143 cites W2020123676 @default.
- W2994830143 cites W2022665712 @default.
- W2994830143 cites W2032095973 @default.
- W2994830143 cites W2048031688 @default.
- W2994830143 cites W2054980098 @default.
- W2994830143 cites W2064850127 @default.
- W2994830143 cites W2076147329 @default.
- W2994830143 cites W2078745866 @default.
- W2994830143 cites W2086179339 @default.
- W2994830143 cites W2113998380 @default.
- W2994830143 cites W2124145627 @default.
- W2994830143 cites W2125914478 @default.
- W2994830143 cites W2139384784 @default.
- W2994830143 cites W2150544187 @default.
- W2994830143 cites W2167291538 @default.
- W2994830143 cites W2320041727 @default.
- W2994830143 cites W2330072781 @default.
- W2994830143 cites W2331822952 @default.
- W2994830143 cites W2464831798 @default.
- W2994830143 cites W2494879671 @default.
- W2994830143 cites W2563658519 @default.
- W2994830143 cites W2567936328 @default.
- W2994830143 cites W2584580415 @default.
- W2994830143 cites W2610595204 @default.
- W2994830143 cites W2741666878 @default.
- W2994830143 cites W2785125360 @default.
- W2994830143 cites W2788919210 @default.
- W2994830143 cites W2903091436 @default.
- W2994830143 cites W2920940294 @default.
- W2994830143 cites W2950152152 @default.
- W2994830143 cites W2950832025 @default.
- W2994830143 cites W2950977925 @default.
- W2994830143 cites W2951321581 @default.
- W2994830143 cites W2951998780 @default.
- W2994830143 cites W2952036937 @default.
- W2994830143 cites W2963108717 @default.
- W2994830143 cites W2984002787 @default.
- W2994830143 cites W2004308929 @default.
- W2994830143 doi "https://doi.org/10.1021/acs.joc.9b02992" @default.
- W2994830143 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31845808" @default.
- W2994830143 hasPublicationYear "2019" @default.
- W2994830143 type Work @default.
- W2994830143 sameAs 2994830143 @default.
- W2994830143 citedByCount "7" @default.
- W2994830143 countsByYear W29948301432020 @default.
- W2994830143 countsByYear W29948301432021 @default.
- W2994830143 countsByYear W29948301432022 @default.
- W2994830143 countsByYear W29948301432023 @default.
- W2994830143 crossrefType "journal-article" @default.
- W2994830143 hasAuthorship W2994830143A5006528597 @default.
- W2994830143 hasAuthorship W2994830143A5020803502 @default.
- W2994830143 hasAuthorship W2994830143A5027792053 @default.
- W2994830143 hasAuthorship W2994830143A5029400180 @default.
- W2994830143 hasAuthorship W2994830143A5067010720 @default.
- W2994830143 hasAuthorship W2994830143A5077367725 @default.
- W2994830143 hasAuthorship W2994830143A5082704360 @default.
- W2994830143 hasAuthorship W2994830143A5090815103 @default.
- W2994830143 hasAuthorship W2994830143A5091103434 @default.
- W2994830143 hasConcept C142724271 @default.
- W2994830143 hasConcept C161790260 @default.
- W2994830143 hasConcept C178790620 @default.
- W2994830143 hasConcept C185592680 @default.
- W2994830143 hasConcept C204787440 @default.
- W2994830143 hasConcept C21951064 @default.
- W2994830143 hasConcept C2776910235 @default.
- W2994830143 hasConcept C2777332933 @default.
- W2994830143 hasConcept C2991944050 @default.
- W2994830143 hasConcept C521977710 @default.
- W2994830143 hasConcept C71924100 @default.
- W2994830143 hasConceptScore W2994830143C142724271 @default.
- W2994830143 hasConceptScore W2994830143C161790260 @default.
- W2994830143 hasConceptScore W2994830143C178790620 @default.
- W2994830143 hasConceptScore W2994830143C185592680 @default.
- W2994830143 hasConceptScore W2994830143C204787440 @default.
- W2994830143 hasConceptScore W2994830143C21951064 @default.
- W2994830143 hasConceptScore W2994830143C2776910235 @default.
- W2994830143 hasConceptScore W2994830143C2777332933 @default.