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- W3035991778 abstract "We prepared a metastable polymorph of vinyl ethylene carbonate by inducing crystallization of the supercooled liquid via an electric field of about 80 kV cm–1. Electric fields with sufficiently low frequencies are required to observe polymorphism for this material. Depending on the temperature protocol prior to crystallization, the field-induced crystal structure can be obtained either with high polymorphic purity or mixed with seed crystals of the ordinary stable polymorph. At the crystallization temperature of Tc = 198 K, the pure field-induced polymorph shows no sign of a polymorphic transition, while at the same temperature, this crystal structure converts to the stable state in a matter of several hours if seeded by the stable polymorph. Interestingly, we find that the permittivity changes linearly with the volume fraction of the field-induced polymorph during the conversion, so that the polymorph transition can be followed in real time by dielectric techniques." @default.
- W3035991778 created "2020-06-25" @default.
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- W3035991778 date "2020-06-17" @default.
- W3035991778 modified "2023-10-09" @default.
- W3035991778 title "Watching the Polymorphic Transition from a Field-Induced to a Stable Crystal by Dielectric Techniques" @default.
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- W3035991778 doi "https://doi.org/10.1021/acs.cgd.0c00626" @default.
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