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- W3046351720 abstract "Abstract Two series of new coordination polymers (CPs) based on trivalent lanthanoids and 4-(pyridyl-N-oxide)methylphosphonic acid (H2L), namely, {[Ln2(L)2(H2O)5]2Cl·2H2O}n (Ln = Eu(1), Tb(2), Dy(3)) and [Ln(L)(OH)(H2O)]n (Ln = Eu(4), Tb(5), Dy(6)) have been obtained under hydrothermal conditions and characterized by single-crystal X-ray diffraction(SXRD), powder X-ray diffraction(PXRD) and so on. The single-crystal X-ray diffraction results show that complexes 1–3 are isomorphic with 3D framework structures, while isomorphic complexes 4–6 show 2D layered structures. Photoluminescent spectra of complexes 1 and 2 exhibits the strong luminescence characteristic of Eu(III) and Tb(III) ions, respectively. Interestingly, complex 1 can act as a sensor baesd on fluorescence sensing method for detecting trans, trans-muconic acid (tt-MA), biomarker of benzene, with excellent sensitivity, great selectivity and the low LOD for tt-MA which is 2.89 μM. However, the magnetic behaviors of complexes 2, 3, 5 and 6 reveal the presence of antiferromagnetic between the lanthanoid ions." @default.
- W3046351720 created "2020-08-07" @default.
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- W3046351720 date "2020-10-01" @default.
- W3046351720 modified "2023-10-18" @default.
- W3046351720 title "Highly selective and sensitive lanthanoids coordination polymers sensors for trans, trans-muconic acid, a biomarker of benzene" @default.
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- W3046351720 doi "https://doi.org/10.1016/j.poly.2020.114728" @default.
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