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• W3103497984 abstract "This report describes the α-stereoselective addition of alcohols to glycals promoted by a cooperative Lewis acid/base pair catalytic system composed of B(C6F5)3 and tetrabutylammonium bromide (TBAB), which provides access to 2-deoxylglycosides in high yields. A mechanistic investigation supported by NMR analysis highlights the possible involvement of nucleophilic addition through boron-induced activation of alcohols under the assistance of TBAB. The protocol discussed here features the high stereoselectivity, mild reaction conditions, inexpensive and stable catalysts, and a broad substrate scopes." @default.
• W3103497984 created "2020-11-23" @default.
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• W3103497984 date "2020-12-01" @default.
• W3103497984 modified "2023-09-23" @default.
• W3103497984 title "Lewis acid/base pair as a catalytic system for α-stereoselective synthesis of 2-deoxyglycosides through the addition of alcohols to glycals" @default.
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• W3103497984 doi "https://doi.org/10.1016/j.tetlet.2020.152643" @default.
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