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- W3114383414 abstract "A new nitronyl nitroxide-Tb(III) complex, [Tb(hfac)3(NIT-3-Br-4Py)2] (1) (hfac = hexafluoroacetyl -acetonate, NIT-3-Br-4Py = 2-(3′-bromo-4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide), has been synthesized and characterized. The single-crystal X-ray diffraction analysis shows it crystallizes in monoclinic C2/c space group, and is composed of mononuclear molecules. The central Tb(III) ion is eight-coordinated by three bidentate chelating hfac anions and two monodentate NITR ligands, with a dodecahedron environment. Ac magnetic susceptibility study shows that complex 1 exhibits slow magnetic relaxation, suggesting single-molecule magnet behavior." @default.
- W3114383414 created "2021-01-05" @default.
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- W3114383414 date "2021-04-01" @default.
- W3114383414 modified "2023-10-03" @default.
- W3114383414 title "Magnetic slow relaxation of Tb(III) complex with a nitronyl nitroxide involving a brominated-pyridyl substituent" @default.
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- W3114383414 doi "https://doi.org/10.1016/j.molstruc.2020.129807" @default.
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