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- W3124569613 abstract "Abstract The metal‐free catalytic hydrogenation of secondary carboxylic acid amides is developed. The reduction is realized by two new catalytic reactions. First, the amide is converted into the imidoyl chloride by triphosgene (CO(OCCl 3 ) 2 ) using novel phosphorus(V) catalysts. Second, the in situ generated imidoyl chlorides are hydrogenated in high yields by an FLP‐catalyst. Mechanistic and quantum mechanical calculations support an autoinduced catalytic cycle for the hydrogenation with chloride acting as unusual Lewis base for FLP‐mediated H 2 ‐activation." @default.
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- W3124569613 date "2021-09-02" @default.
- W3124569613 modified "2023-10-03" @default.
- W3124569613 title "Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis" @default.
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- W3124569613 doi "https://doi.org/10.1002/chem.202100041" @default.
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