Matches in SemOpenAlex for { <https://semopenalex.org/work/W3205361635> ?p ?o ?g. }
- W3205361635 abstract "Computational crystal-field models have provided consistent models of both electronic and Zeeman-hyperfine structure for several rare earth ions. These techniques have not yet been applied to the Zeeman-hyperfine structure of Eu$^{3+}$ because modeling the structure of the $J=0$ singlet levels in Eu$^{3+}$ requires inclusion of the commonly omitted lattice electric quadrupole and nuclear Zeeman interactions. Here, we include these terms in a computational model to fit the crystal field levels and the Zeeman-hyperfine structure of the $^7F_0$ and $^5D_0$ states in three Eu$^{3+}$ sites: the C$_{4v}$ and C$_{3v}$ sites in CaF$_2$ and the C$_2$ site in EuCl$_3$.6H$_2$O. Close fits are obtained for all three sites which are used to resolve ambiguities in previously published parameters, including quantifying the anomalously large crystal-field-induced state mixing in the C$_{3v}$ site and determining the signs of Zeeman-hyperfine parameters in all three sites. We show that this model allows accurate prediction of properties for Eu$^{3+}$ important for quantum information applications of these ions, such as relative transition strengths. The model could be used to improve crystal field calculations for other non-Kramers singlet states. We also present a spin Hamiltonian formalism without the normal assumption of no $J$ mixing, suitable for other rare earth ion energy levels where this effect is important." @default.
- W3205361635 created "2021-10-25" @default.
- W3205361635 creator A5006084321 @default.
- W3205361635 creator A5021580767 @default.
- W3205361635 creator A5041105991 @default.
- W3205361635 creator A5083736781 @default.
- W3205361635 date "2022-03-30" @default.
- W3205361635 modified "2023-09-25" @default.
- W3205361635 title "Complete crystal-field calculation of Zeeman hyperfine splittings in europium" @default.
- W3205361635 cites W1485529961 @default.
- W3205361635 cites W1512682366 @default.
- W3205361635 cites W1619469341 @default.
- W3205361635 cites W1657021756 @default.
- W3205361635 cites W1749126883 @default.
- W3205361635 cites W1964699069 @default.
- W3205361635 cites W1965422661 @default.
- W3205361635 cites W1965927183 @default.
- W3205361635 cites W1968088135 @default.
- W3205361635 cites W1970146484 @default.
- W3205361635 cites W1975286387 @default.
- W3205361635 cites W1981255180 @default.
- W3205361635 cites W1986120256 @default.
- W3205361635 cites W1986123631 @default.
- W3205361635 cites W1987399725 @default.
- W3205361635 cites W1987738152 @default.
- W3205361635 cites W1989297739 @default.
- W3205361635 cites W1990757861 @default.
- W3205361635 cites W1992040647 @default.
- W3205361635 cites W1996101925 @default.
- W3205361635 cites W1997198956 @default.
- W3205361635 cites W2001247121 @default.
- W3205361635 cites W2007180258 @default.
- W3205361635 cites W2007862804 @default.
- W3205361635 cites W2008391764 @default.
- W3205361635 cites W2008924194 @default.
- W3205361635 cites W2013225595 @default.
- W3205361635 cites W2018203508 @default.
- W3205361635 cites W2019418813 @default.
- W3205361635 cites W2021405721 @default.
- W3205361635 cites W2026450874 @default.
- W3205361635 cites W2031116388 @default.
- W3205361635 cites W2038115097 @default.
- W3205361635 cites W2041051878 @default.
- W3205361635 cites W2043740335 @default.
- W3205361635 cites W2044611643 @default.
- W3205361635 cites W2045862124 @default.
- W3205361635 cites W2046970141 @default.
- W3205361635 cites W2055861144 @default.
- W3205361635 cites W2064415703 @default.
- W3205361635 cites W2065460144 @default.
- W3205361635 cites W2075501792 @default.
- W3205361635 cites W2078640875 @default.
- W3205361635 cites W2078883245 @default.
- W3205361635 cites W2080527789 @default.
- W3205361635 cites W2085113003 @default.
- W3205361635 cites W2086643495 @default.
- W3205361635 cites W2088760726 @default.
- W3205361635 cites W2091687864 @default.
- W3205361635 cites W2093124612 @default.
- W3205361635 cites W2093556881 @default.
- W3205361635 cites W2095288403 @default.
- W3205361635 cites W2117000100 @default.
- W3205361635 cites W2127119100 @default.
- W3205361635 cites W2318936054 @default.
- W3205361635 cites W2321839967 @default.
- W3205361635 cites W2508561013 @default.
- W3205361635 cites W2907207720 @default.
- W3205361635 cites W2954595148 @default.
- W3205361635 cites W2965330946 @default.
- W3205361635 cites W2991761044 @default.
- W3205361635 cites W2995267529 @default.
- W3205361635 cites W3105621768 @default.
- W3205361635 cites W3136396883 @default.
- W3205361635 cites W3207459814 @default.
- W3205361635 cites W4214498476 @default.
- W3205361635 doi "https://doi.org/10.1103/physrevb.105.125141" @default.
- W3205361635 hasPublicationYear "2022" @default.
- W3205361635 type Work @default.
- W3205361635 sameAs 3205361635 @default.
- W3205361635 citedByCount "1" @default.
- W3205361635 countsByYear W32053616352023 @default.
- W3205361635 crossrefType "journal-article" @default.
- W3205361635 hasAuthorship W3205361635A5006084321 @default.
- W3205361635 hasAuthorship W3205361635A5021580767 @default.
- W3205361635 hasAuthorship W3205361635A5041105991 @default.
- W3205361635 hasAuthorship W3205361635A5083736781 @default.
- W3205361635 hasBestOaLocation W32053616352 @default.
- W3205361635 hasConcept C115260700 @default.
- W3205361635 hasConcept C121332964 @default.
- W3205361635 hasConcept C126255220 @default.
- W3205361635 hasConcept C130787639 @default.
- W3205361635 hasConcept C131538251 @default.
- W3205361635 hasConcept C145148216 @default.
- W3205361635 hasConcept C181500209 @default.
- W3205361635 hasConcept C184779094 @default.
- W3205361635 hasConcept C199360897 @default.
- W3205361635 hasConcept C25227350 @default.
- W3205361635 hasConcept C26873012 @default.
- W3205361635 hasConcept C2781285689 @default.
- W3205361635 hasConcept C33062035 @default.