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• W3205701971 abstract "By first principles simulations we systematically investigate Se hyperdoped silicon by computing, for different types of Se complexes, the formation energy as a function of dopant concentration. We identify the microscopic mechanisms responsible for the dramatic reduction of electrical deactivation defects as the dopant concentration approaches the critical value, xc, at which the insulator-to-metal transition occurs. We discuss the electrical properties of Se point defects and Se complexes, shedding light on the formation and the nature of the impurity band in the bandgap and how the presence of different types of complexes may increase the broadening of the impurity band and affects the insulator-to-metal transition. We identify the best doping range in which the properties of the impurity band can be engineered according to the needs of the electronic industry. Simulations of the structural properties of the complexes complete the work. Our findings are relevant for intermediate impurity band applications." @default.
• W3205701971 created "2021-10-25" @default.
• W3205701971 creator A5043431986 @default.
• W3205701971 date "2021-01-01" @default.
• W3205701971 modified "2023-10-16" @default.
• W3205701971 title "First principles simulations of microscopic mechanisms responsible for the drastic reduction of electrical deactivation defects in Se hyperdoped silicon" @default.
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• W3205701971 doi "https://doi.org/10.1039/d1cp02899e" @default.
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