Matches in SemOpenAlex for { <https://semopenalex.org/work/W3211610175> ?p ?o ?g. }
- W3211610175 endingPage "6690" @default.
- W3211610175 startingPage "6690" @default.
- W3211610175 abstract "Electrolytes based on ionic liquids (IL) are promising candidates to replace traditional liquid electrolytes in electrochemical systems, particularly in combination with carbon-based porous electrodes. Insight into the dynamics of such systems is imperative for tailoring electrochemical performance. In this work, 1-Methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-Hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide were studied in a carbon black (CB) host using spectrally resolved Carr-Purcell-Meiboom-Gill (CPMG) and 13-interval Pulsed Field Gradient Stimulated Echo (PFGSTE) Magic Angle Spinning Nuclear Magnetic Resonance (MAS-NMR). Data were processed using a sensitivity weighted Laplace inversion algorithm without non-negativity constraint. Previously found relations between the alkyl length and the aggregation behavior of pyrrolidinium-based cations were confirmed and characterized in more detail. For the IL in CB, a different aggregation behavior was found compared to the neat IL, adding the surface of a porous electrode as an additional parameter for the optimization of IL-based electrolytes. Finally, the suitability of MAS was assessed and critically discussed for investigations of this class of samples." @default.
- W3211610175 created "2021-11-22" @default.
- W3211610175 creator A5029944987 @default.
- W3211610175 creator A5036475951 @default.
- W3211610175 creator A5073004779 @default.
- W3211610175 creator A5075877965 @default.
- W3211610175 date "2021-11-05" @default.
- W3211610175 modified "2023-09-30" @default.
- W3211610175 title "MAS-NMR of [Pyr13][Tf2N] and [Pyr16][Tf2N] Ionic Liquids Confined to Carbon Black: Insights and Pitfalls" @default.
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