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• W4205807776 abstract "Abstract We describe a simplified method to synthesize film forming polymer Janus particles by phase separation during RAFT-based free radical emulsion polymerization. Fully crosslinked snowman- or football-shaped polystyrene Janus particles (PSJPs) were first produced in a one-step batch process using amphiphilic triblock macro-RAFT copolymers as stabilizers. Such particles were in turn employed as seeds in a continuous emulsion polymerization in which a monomer mixture of methyl methacrylate (MMA) and butyl acrylate (BA) (1/1 by weight) was constantly injected into the reaction in the presence of a water soluble initiator. The added monomers wetted seed particle surface and their polymerization led to formations of 93-nm film forming single- or two-headed Janus particles. The resulted latex was successfully used to disperse and encapsulate solid calcite extender. Graphical abstract" @default.
• W4205807776 created "2022-01-25" @default.
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• W4205807776 date "2022-01-11" @default.
• W4205807776 modified "2023-10-14" @default.
• W4205807776 title "Janus particles by simplified RAFT-based emulsion polymerization process for polymer coating" @default.
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• W4205807776 doi "https://doi.org/10.1007/s00396-021-04939-x" @default.
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