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• W4240532892 abstract "A Palladium 1–2 Punch Methods to replace carbon-hydrogen bonds directly with carbon-carbon bonds offer enticing prospects for streamlining the synthesis of organic compounds. The trouble is that it is hard to select any particular C-H bond and to avoid making complex mixtures of products. He et al. (p. 1216 ) report that a pair of powerful pyrimidine ligands induces a palladium catalyst to add aryl groups selectively to amino acid derivatives. One ligand promotes addition of a single aryl group to the β-carbon center; the other appends a second, potentially different aryl group to the same carbon—all in the same flask." @default.
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• W4240532892 date "2014-03-14" @default.
• W4240532892 modified "2023-10-01" @default.
• W4240532892 title "Ligand-Controlled C(sp ³ )–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids" @default.
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• W4240532892 doi "https://doi.org/10.1126/science.1249198" @default.
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