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- W4308588384 abstract "Abstract The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic C(sp 3 )−H bond has been achieved for the first time during a silver‐catalyzed carbene/alkyne metathesis (CAM) process. A Tp x ‐containing silver complex first promotes the generation of a donor‐acceptor silver carbene which triggers CAM, generating a subsequent donor‐donor vinyl silver carbene species, which then undergoes a selective vinylogous C(sp 3 )−H bond insertion, leading to the synthesis of a new family of benzoazepines. Density functional theory (DFT) calculations unveil the reaction mechanism, which allows proposing that the C−H bond insertion reaction takes place in a stepwise manner, with the hydrogen shift being the rate determining step." @default.
- W4308588384 created "2022-11-12" @default.
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- W4308588384 date "2022-12-22" @default.
- W4308588384 modified "2023-10-16" @default.
- W4308588384 title "Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp <sup>3</sup> )−H Bond Insertion" @default.
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- W4308588384 doi "https://doi.org/10.1002/ange.202215163" @default.
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